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31
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Course No.
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Course Title
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No. of Units
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Pre-requisites
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Th.
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Pr.
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Credit
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Chem 425
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Organo-metallic Chemistry
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2
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-
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2
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Chem 322
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Course objective :
A
course intended to give an overall view of organometallic compounds,
their syntheses, structure, bonding, and major uses in homogeneous and
heterogeneous catalysis .
Course Description
CO
molecule, unsaturated carbon chains and rings and the formation of
metal-carbon bonds, IUPAC nomenclature, the concept of back-bonding,
electro neutrality and the 18-e- rule, s-bonded complexes (carbonyls, alkyls, hydrides etc...), p-bonded
complexes (ferrocines, alkenes, alkynes, allyles, etc...),
stereochemistry and simple MO-bonding, syntheses and reactions of
organo-metallic compounds, characterization by i.r., 1H nmr and 13C nmr., metal nitrosyls and dinitrogen complexes, homogeneous and heterogeneous catalysis, applications in organic syntheses .
Main text books :
§ Organometallic Chemistry, G. O. Spessard, G. L. Missler, 1996, Prentice-Hall .
§
Subsidiary books :
§ The Organometallic Chemistry of the Transition Metals, R. H. Crabtree, 3rd ed., 2000, John Wiley & Sons.
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